Investigation of the Pyrolysis Behaviour of Marine Macroalgae Biomass Using the Thermogravimetric Analysis
Downloads
Macroalgae could be significant marine biomass resource for the production of numerous energy carriers including biofuels. In this research work, the kinetic characteristics of a red macroalgae, (Gelidium sesquipedale) as a model for marine biomass were evaluated and compared at heating rates of 2, 10, 20 and 50 °C min-1 under an inert atmosphere. The results indicated that three stages appeared during pyrolys is, moisture evaporation, primary devolatilization and residual decomposition. The heating rates slightly affect the decomposition properties of Gelidium sesquipedale; with the heating rates increasing, the maximum peak of weight lossrate shifted to higher temperatures. The Friedman isoconventional method was used to obtain the kinetic parameters from data of the pyrolysis reactions of in the second zone. The average activation energy of Gelidium sesquipedale was 228,45±7 kJ mol-1.These data provideinformation for further application for designing and modelling in thermo chemical conversion system of Gelidium sesquipedale.
Ross AB, Jones JM, Kubacki ML, Bridgeman T. Classification of macroalgae as fuel and its thermochemical behaviour. Bioresource Technology. 99(14), 6494–6504 (2008).
Demirbas A. Use of algae as biofuel sources. Energy Conversion and Management. 51(12), 2738–2749 (2010).
Adams JMM, Ross AB, Anastasakis K, et al. Seasonal variation in the chemical composition of the bioenergy feedstock Laminaria digitata for thermochemical conversion. Bioresource Technology. 102(1), 226–234 (2011).
Lee J-H, Lee D-G, Park J-I, Kim J-Y. Bio-hydrogen production from a marine brown algae and its bacterial diversity. Korean J. Chem. Eng. 27(1), 187–192 (2010).
Shafizadeh F, McGinnis GD. Chemical composition and thermal analysis of cottonwood. Carbohydrate Research. 16(2), 273–277 (1971).
Wu K, Liu J, Wu Y, et al. Pyrolysis characteristics and kinetics of aquatic biomass using thermogravimetric analyzer. Bioresource Technology. 163, 18–25 (2014).
Ceylan S, Topcu Y, Ceylan Z. Thermal behaviour and kinetics of alga Polysiphonia elongata biomass during pyrolysis. Bioresource Technology. 171, 193–198 (2014).
Zhao H, Yan H, Dong S, et al. Thermogravimetry study of the pyrolytic characteristics and kinetics of macro-algae Macrocystis pyrifera residue. J Therm Anal Calorim. 111(3), 1685–1690 (2013).
Li D, Chen L, Zhang X, Ye N, Xing F. Pyrolytic characteristics and kinetic studies of three kinds of red algae. Biomass and Bioenergy. 35(5), 1765–1772 (2011).
Kim S-S, Ly HV, Kim J, Choi JH, Woo HC. Thermogravimetric characteristics and pyrolysis kinetics of Alga Sagarssum sp. biomass. Bioresource Technology. 139, 242–248 (2013).
Anastasakis K, Ross AB, Jones JM. Pyrolysis behaviour of the main carbohydrates of brown macro-algae. Fuel. 90(2), 598–607 (2011).
Friedman HL. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. J. polym. sci., C Polym. symp. 6(1), 183–195 (1964).
Aboulkas A, El Harfi K. Co-pyrolysis of olive residue with poly(vinyl chloride) using thermogravimetric analysis. J Therm Anal Calorim. 95(3), 1007 (2008).
Guida MY, Bouaik H, Tabal A, et al. Thermochemical treatment of olive mill solid waste and olive mill wastewater. J Therm Anal Calorim. 123(2), 1657–1666 (2016).
Radhakumari M, Prakash DJ, Satyavathi B. Pyrolysis characteristics and kinetics of algal biomass using tga analysis based on ICTAC recommendations. Biomass Conv. Bioref. 6(2), 189–195 (2016).
Yanik J, Stahl R, Troeger N, Sinag A. Pyrolysis of algal biomass. Journal of Analytical and Applied Pyrolysis. 103, 134–141 (2013).
Pyrolysis characteristics and kinetics of the alga Saccharina japonica - ScienceDirect [Internet]. Available from:
https://www.sciencedirect.com/science/article/pii/S0960852412011510.
Ferrera-Lorenzo N, Fuente E, Suárez-Ruiz I, Gil RR, Ruiz B. Pyrolysis characteristics of a macroalgae solid waste generated by the industrial production of Agar–Agar. Journal of Analytical and Applied Pyrolysis. 105, 209–216 (2014).
Bae YJ, Ryu C, Jeon J-K, et al. The characteristics of bio-oil produced from the pyrolysis of three marine macroalgae. Bioresource technology. 102(3), 3512–3520 (2011).