Activated Carbon Prepared from Date Pits Using Microwave Heating
Downloads
Activated carbon (AC) adsorption remains one of the most technically efficient water treatment processes. However, its high preparation cost, mainly due to energy-intensive methods, has led to research on developing efficient and cost-effective preparation methods using less expensive materials such as agricultural waste. The objective of our study was to use date pits for the preparation of AC that can be used for water treatment (Adsorption and elimination of dyes). For the activation process, a microwave radiation under steam method was employed. The AC prepared from date pits /H3PO4/carbonization 400°C using the steam-microwave radiation activation technique (radiation time: 15 minutes, power: 700W) demonstrated promising results. The adsorption tests show 80% removal rate of the reactive dye (Drimaren ROT CL-5B GR) from water. This study highlights the potential of date pits as a viable source for producing AC from bio-material. The obtained product was analysed by FTIR and MEB.
Bubanale S. , & Shivashankar M. (2017). History, Method of Production, Structure and Applications of Activated Carbon. IIJERT. 6.
http://dx.doi.org/10.17577/IJERTV6IS060277
Jagtoyen, M., & Derbyshire, F. (1998). Activated carbon from yellow poplar and white oak by H3PO4 activation. Carbon, 36, pp. 1085-1097.
https://doi.org/10.1016/S0008-6223(98)00082-7
Evwierhoma, E. T., Madubiko O. D. & Jaiyeola, A., (2018), Preparation and characterization of activated carbon from bean husk , nijotech. 37, 3, pp. 674-678. https://doi.org/10.4314/njt.v37i3.17
Manjula Devi M. & Manonmani, S. (2015), Removal of Hexavalent Chromium Ions from Aqueous Solution by Adsorption Using Activated Carbon Prepared from Cucumis Melo Peel Activated carbon, Oriental journal of chemistry, 31, 1 pp. 531-539.
http://dx.doi.org/10.13005/ojc/310166
Horikawa, T., Kitakaze, Y., Sekida, T., Hayashi, J. & Katoh, M. (2010), Characteristics and humidity control capacity of activated carbon from bamboo. Bioresource Technology, 101 pp. 3964-3969. https://doi.org/10.1016/j.biortech.2010.01.032
Ouattara Kra D., Allou N. B., Atheba P., Drogui P., & Trokourey A. (2019). Preparation and Characterization of Activated Carbon Based on Wood (Acacia auriculeaformis, Côte d’Ivoire). Journal of Encapsulation and Adsorption Sciences, 9, pp. 63-82.
https://doi.org/10.4236/jeas.2019.92004
Duran-Valle, C.J., Gomez-Corzo, M., Pastor-Villegas, J.,& Gomez-Serrano, V. (2005). Study of cherry stones as raw material in preparation of carbonaceous adsorbents. Journal of Analytical and Applied Pyrolysis, 73, 1, pp. 59-67. http://dx.doi.org/10.1016/j.jaap.2004.10.004
Alcaraz, L., Lopez Fernandez A., Garcıa-Dıaz I., & Felix A Lopez F.A. (2018). Preparation and characterization of activated carbons from winemaking wastes and their adsorption of methylene blue, Adsorption Science & Technology, 36(5–6), pp. 1331–1351.
https://doi.org/10.1177/0263617418770295
Elmaslar, E., Özbaşa, Balçıkb , B., & Ozcana , H.K. (2019). Preparation of activated carbon from waste tires, and its use for dye removal. Desalination and Water Treatment, 172, pp.78–85. http://dx.doi.org/10.5004/dwt.2019.24493
Deng, H., Zhang, G., Xu, X., Tao, G., & Dai, J. (2010). Optimization of preparation of activated carbon from cotton stalk by microwave assisted phosphoric acid – chemical activation. Journal of Hazardous Materials, 182, pp. 217-224.
https://doi.org/10.1016/j.jhazmat.2010.06.018
Deng, H., Li, G., Yang, H., & Tang, J. (2010). Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation. Chemical Engineering Journal, 163, pp. 373-381. http://dx.doi.org/10.1016/j.cej.2010.08.019
Foo, K.Y., & Hameed, B.H. (2011). Microwave assisted preparation of activated carbon from pomelo skin for the removal of anionic and cationic dyes. Chemical Engineering Journal, 173, 2, pp. 385-390. https://doi.org/10.1016/j.cej.2011.07.073
Wang, X., Liang, X., Wang, Y., Wang, X., Liu, M., Yin, D., Xia, S., Zhao, J., & Zhang, Y. (2011). Adsorption of copper (II) onto activated carbons from sewage sludge by microwave-induced phosphoric acid and zinc chloride activation. Desalination, 278 (1-3), pp. 231-237. https://doi.org/10.1039/C0JM02963G
Cheng S., Zhang S., Zhang L., Xia H., Peng J. & Wang, S. (2017). Microwave-Assisted Preparation of Activated Carbon from Eupatorium Adenophorum: Effects of Preparation Parameters. High Temp. Mater. Proc., 36, 8 pp. 805–814. https://doi.org/10.1016/j.tifs.2017.07.007
Norakmalah Mohd Zawawi, Fazlena Hamzah, Mahanim Sarif, Shareena Fairuz Abdul Manaf, & Ani Idris (2017). Characterization of activated carbon using chemical activation via microwave ultrasonic system .Malaysian Journal of Analytical Sciences, 21, 1, pp. 159 – 165. DOI: 10.175/mjas-2017-2101-18. http://dx.doi.org/10.17576/mjas-2017-2101-18
Banat, F., Al-Asheh, S., & Al-Mahadmeh, L. (2003). Evaluation of the use of raw and activated date pits as potential adsorbants for dye containing waters. Process Biochemistry.39, pp.193-202. https://doi.org/10.1016/S0032-9592(03)00065-7
Girgis, B.S., & EI-Hendawy, A.N.A. (2002) Porosity development in activated carbons obtained from date pits under chemical activation with phosphoric acid. Microporous and Mesoporous Materials, 52, pp. 105-117.
https://doi.org/10.1016/S1387-1811(01)00481-4
Haimour, N.M., & Emeish, S., (2006). Utilization of date stones for production of activated carbon using phosphoric acid. Waste Management, 26,6, pp. 651-660.
https://doi.org/10.1016/j.wasman.2005.08.004
Belguedj M. (1996). Caractéristiques des cultivars du dattier du sud est du Sahara algérien. pp. 3- 51.