Boosting the Microwave Absorption Properties Using Graphene Functionalized with Mg-Mn-Zn-Bi Ferrites
Downloads
Graphene (Gr) composites with Mg0.5Mn0.375Zn0.125Bi0.05Fe1.95O4 (MMZB nano ferrites), (Gr= 0%, 1%, 2%, 3%, 4%) were synthesized by using the sol gel auto combustion method. XRD, FTIR and Uv-Vis confirmed the significant improvement in structural, vibrational and optical properties of MMZB ferrites\Gr composites with fusion of Gr. The lattice parameter ‘a’ varies with increasing Gr concertation. From the FT-IR spectra the absorption bands observed in the range of 541-563 cm-1 and 421-461 cm-1 are attributed to the fusion of Gr in MMZB Ferrite/Gr Composites. The d.c resistivity of ferrite samples increased as the temperature increased in ferromagnetic region up to curie temperature, after that its decreased. However, increase in resistivity was observed with increasing Gr concentration except at Gr = 3%. The values of optical band gap were found to decreased from 4.45 to 3.50 eV with increasing Gr content. It has been observed that both the dielectric constant and loss factor decreased with the increase of frequency. The minimum dielectric loss was observed for Gr =4 %. The values of saturation magnetization and microwave frequency decreases with fusion of Gr. A remarkable change in microstructures, electrical and magnetic properties was observed with fusion of Gr. Due to these promising properties these materials may be used for microwave frequency devices.
Humaira, A., & Asghari, M. (2013). Frequency dependent dielectric measurements of Cd2+ doped Mn-Zn nano ferrites prepared by sol gel and coprecipitation methods. In Journal of Physics: Conference Series (Vol. 439, No. 1, p. 012014). IOP Publishing.
Batoo, K. M. (2011). Study of dielectric and impedance properties of Mn ferrites. Physica B: Condensed Matter, 406(3), 382-387
Routray, K. L., Sanyal, D., & Behera, D. (2019). Gamma irradiation induced structural, electrical, magnetic and ferroelectric transformation in bismuth doped nanosized cobalt ferrite for various applications. Materials Research Bulletin, 110, 126-134.
Farid, H. M. T., Ahmad, I., Bhatti, K. A., Ali, I., Ramay, S. M., & Mahmood, A. (2017). The effect of praseodymium on Cobalt-Zinc spinel ferrites. Ceramics International, 43(9), 7253-7260.
Bhukal, S., Mor, S., Bansal, S., Singh, J., & Singhal, S. (2014). Influence of Cd2+ ions on the structural, electrical, optical and magnetic properties of Co–Zn nanoferrites prepared by sol gel auto combustion method. Journal of Molecular Structure, 1071, 95-102.
Zaharieva, K., Rives, V., Tsvetkov, M., Cherkezova-Zheleva, Z., Kunev, B., Trujillano, R., ... & Milanova, M. (2015). Preparation, characterization and application of nanosized copper ferrite photocatalysts for dye degradation under UV irradiation. Materials Chemistry and Physics, 160,
Reddy, C. V., Byon, C., Narendra, B., Baskar, D., Srinivas, G., Shim, J., & Vattikuti, S. P. (2015). Investigation of structural, thermal and magnetic properties of cadmium substituted cobalt ferrite nanoparticles. Superlattices and Microstructures, 82, 165-173.
Hamdaoui, N., Azizian-Kalandaragh, Y., Khlifi, M., & Beji, L. (2019). Cd-doping effect on morphologic, structural, magnetic and electrical properties of Ni0. 6-xCdxMg0. 4Fe2O4 spinel ferrite (0≤ x≤ 0.4). Journal of Alloys and Compounds, 803, 964-970.
Singhal, S., Bhukal, S., Singh, J., Chandra, K., & Bansal, S. (2011). Optical, X-Ray Diffraction, and Magnetic Properties of the Cobalt-Substituted Nickel Chromium Ferrites (CrCox Ni1-x FeO4, x= 0, 0.2, 0.4, 0.6, 0.8, 1.0) Synthesized Using Sol-Gel Autocombustion Method. Journal of Nanotechnology, 2011.
Sagadevan, S., Podder, J., & Das, I. (2016). Hydrothermal synthesis of zirconium oxide nanoparticles and its characterization. Journal of Materials Science: Materials in Electronics, 27(6), 5622-5627
Sagadevan, S., Pal, K., Chowdhury, Z. Z., & Hoque, M. E. (2017). Structural, optical and dielectric investigation of CdFe2O4 nanoparticles. Materials Research Express, 4(7), 075025.