Relationship between Electrospinning Parameters and Physical Properties of Tubular Structure Nanofibers by Opposite Charge Electrospinning .
April 26, 2023
April 29, 2023
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This study describes the opposite charge electrospun method for preparation of polyacrilonitrile / DMF nanofibrous tubular structure . Constant a processing parameters such as high polymer concentration and high rotational speed mandrel collector with varied the applied voltage and flow rate in wide range to display the effect of each one in determining the diameter , alignment, porosity, mean surface area and mean pores size of nanofibers. Tubular structures were produced from highly aligned continuous and uniform nanofibers through the opposite charge electrospinning methods and effect of each regulating parameter on tubular structure properties were evaluated and characterized using scanning electron microscope (SEM) and Fast Fourier Transform (FFT) and thresholding method. Increasing flow rate of polymer solution considerably increased the diameter of the nanofibers , ranges of the average diameters were larger , the nanofibers diameter distribution were gradually border. Nanofibers diameter on the other hand, decreased as the applied voltage increased, ranges of the average diameters were smaller and the nanofibers diameter distribution were gradually narrower . while increased the porosity % , heights intensity(Y%) and mean surface area (nm2) and decreased the mean pores size (nm) with increased both the applied voltage and flow rate of polymer solution .
Habeeb, S. A., Rajabi, L., & Dabirian, F. (2023). Relationship between Electrospinning Parameters and Physical Properties of Tubular Structure Nanofibers by Opposite Charge Electrospinning . Engineering And Technology Journal, 8(4), 2152–2162. https://doi.org/10.47191/etj/v8i4.09
1. SalehHudin HS, Mohamad EN, Mahadi WN, Muhammad Afifi A. Multiple-jet electrospinning methods for nanofiber processing: A review. Mater. Manuf. Process. 2018 Apr 4;33(5):479-98.
2. Habeeb SA, Rajabi L, Dabirian F. Production of polyacrylonitrile/boehmite nanofibrous composite tubular structures by opposite‐charge electrospinning with enhanced properties from a low‐concentration polymer solution. Polym. Compos. 2020 Apr;41(4):1649-61.
3. Rafiei S, Maghsoodloo S, Noroozi B, Mottaghitalab V, Haghi AK. Mathematical modeling in electrospinning process of nanofibers: a detailed review. Cellul. Chem. Technol. 2013 May 1;47(5):323-38.
4. Habeeb SA, Alobad ZK, Albozahid MA. Effect of zinc oxide loading levels on the cure characteristics, mechanical and aging properties of the epdm rubber. International Journal of Mechanical Engineering and Technology (IJMET). 2019;10(1):133-41.
5. Yuan TT, DiGeorge Foushee AM, Johnson MC, Jockheck-Clark AR, Stahl JM. Development of electrospun chitosan-polyethylene oxide/fibrinogen biocomposite for potential wound healing applications. Nanoscale Res. Lett 2018 Dec;13(1):1-2.
6. Habeeb S, Rajabi L, Dabirian F. Comparing Two Electrospinning Methods in Producing Polyacrylonitrile Nanofibrous Tubular Structures with Enhanced Properties. Iran. J. Chem. Chem. Eng. 2019 Jun 1;38(3):23-42.
7. Shim IK, Jung MR, Kim KH, Seol YJ, Park YJ, Park WH, Lee SJ. Novel three‐dimensional scaffolds of poly (L‐lactic acid) microfibers using electrospinning and mechanical expansion: Fabrication and bone regeneration. J Biomed Mater Res B Appl Biomater. 2010 Oct;95(1):150-60.
8. Xiang P, Li M, Zhang CY, Chen DL, Zhou ZH. Cytocompatibility of electrospun nanofiber tubular scaffolds for small diameter tissue engineering blood vessels. International J. Biol. Macromol. 2011 Oct 1;49(3):281-8.
9. Habeeb SA, Alobad ZK, Albozahid MA. The Effecting of Physical Properties of Inorganic Fillers on Swelling Rate of Rubber Compound: A review Study. Journal of University of Babylon for Engineering Sciences. 2019 Jan 28;27(1):94-104.
10. Dabirian F, Hosseini SA. Novel method for nanofibre yarn production using two differently charged nozzles. Fibres Text. East. Eur. 2009 Jul 1;17(3):45-7.
11. Chen J, Niu Q, Chen G, Nie J, Ma G. Electrooxidation of methanol on Pt@ Ni bimetallic catalyst supported on porous carbon nanofibers. J. Phys. Chem. C. 2017 Jan 26;121(3):1463-71.
12. Albozahid M, Diwan AA, Habeeb SA. The effect of addition graphite filler on mechanical properties of epoxy material. Egyptian Journal of Chemistry. 2021 Oct 1;64(10):5747-54.
13. Mottaghitalab V, Haghi AK. A study on electrospinning of polyacrylonitrile nanofibers. Korean J. Chem. Eng . 2011 Jan;28:114-8.
14. Garg K, Bowlin GL. Electrospinning jets and nanofibrous structures. Biomicrofluidics. 2011 Mar 30;5(1):013403.
15. Zong X, Kim K, Fang D, Ran S, Hsiao BS, Chu B. Structure and process relationship of electrospun bioabsorbable nanofiber membranes. polymer. 2002 Jul 1;43(16):4403-12.
16. Habeeb SA. Impact of Polymeric Solutions Parameters on Morphological Properties of Composite Nanofibers. Journal of University of Babylon for Engineering Sciences. 2021 Oct 24;29(2):115-20.
17. Jacobs V, Anandjiwala RD, Maaza M. The influence of electrospinning parameters on the structural morphology and diameter of electrospun nanofibers. . J. Appl. Polym. Sci, 2010 Mar 5;115(5):3130-6.
18. Ren C. PAN nanofibers and nanofiber reinforced composites, ( M.S. Thesis) University of Nebraska-Lincoln . https://digitalcommons.unl.edu/mechengdiss/59/ ( 2013). Accessed Aug 2013.
19. Panda PK. Ceramic nanofibers by electrospinning technique—A review. T INDIAN CERAM SOC, 2007 Apr 1;66(2):65-76.
20. Deitzel JM, Kleinmeyer J, Harris DE, Tan NB. The effect of processing variables on the morphology of electrospun nanofibers and textiles. Polymer. 2001 Jan 1;42(1):261-72.
21. Habeeb SA, Hasan AS, Ţălu Ş, Jawad AJ. Enhancing the Properties of Styrene-Butadiene Rubber by Adding Borax Particles of Different Sizes. Iran. J. Chem. Chem. Eng. Res. Artic. 2021;40(5).
22. Jalili R, Morshed M, Ravandi SA. Fundamental parameters affecting electrospinning of PAN nanofibers as uniaxially aligned fibers. J. Appl. Polym. Sci., 2006 Sep 15;101(6):4350-7.
23. Thompson CJ, Chase GG, Yarin AL, Reneker DH. Effects of parameters on nanofiber diameter determined from electrospinning model. Polymer. 2007 Nov 2;48(23):6913-22.
24. Wang L, Chang MW, Ahmad Z, Zheng H, Li JS. Mass and controlled fabrication of aligned PVP fibers for matrix type antibiotic drug delivery systems. Chem. Eng.J, 2017 Jan 1;307:661-9.
25. Dippold D, Cai A, Hardt M, Boccaccini AR, Horch R, Beier JP, Schubert DW. Novel approach towards aligned PCL-Collagen nanofibrous constructs from a benign solvent system. . Mater. Sci. Eng. C . 2017 Mar 1;72:278-83.
26. Shalumon KT, Anjana J, Mony U, Jayakumar R, Chen JP. Process study, development and degradation behavior of different size scale electrospun poly (caprolactone) and poly (lactic acid) fibers. J POLYM RES ., 2018 Mar;25:1-9.
27. Abdulkadhim MK, Habeeb SA. The Possibility of Producing Uniform Nanofibers from Blends of Natural Biopolymers., Materials Performance and Characterization 11(1) (,313-323(2022). https://doi.org/10.1520/MPC20220045
28. Faris D, Hadi NJ, Habeeb SA. Effect of rheological properties of (Poly vinyl alcohol/Dextrin/Naproxen) emulsion on the performance of drug encapsulated nanofibers. Materials Today: Proceedings. 2021 Jan 1;42:2725-32.
29 Habeeb SA, Nadhim BA. Removal of Nickel (II) Ions, Low Level Pollutants, and Total Bacterial Colony Count from Wastewater by Composite Nanofibers Film. Sci. Iran. , 2022 Oct 24.
30. Nadhim BA, Habeeb SA. Studying the Physical Properties of Non-Woven Polyacrylonitrile Nanofibers after Adding γ-Fe2O3 Nanoparticles. Egypt. J. Chem.. 2021 Dec 1;64(12):7621-30.
31. Bonani W, Maniglio D, Motta A, Tan W, Migliaresi C. Biohybrid nanofiber constructs with anisotropic biomechanical properties. J Biomed Mater Res B Appl Biomater., 2011 Feb;96(2):276-86.
32. Sreedhara SS, Tata NR. A novel method for measurement of porosity in nanofiber mat using pycnometer in filtration. J Eng Fiber Fabr., 2013 Dec; 8(4) : 155892501300800408.
33. Boppa, V: Characterization of Structure and Tensile Properties of Electrospun Web. (MSc Thesis) Faculty of North Carolina State University, Raleigh, North Carolina. http://www.lib.ncsu.edu/resolver/1840.16/1485 (2009) . Accessed 7 Dec 2009.
34. Ding B, Kim HY, Lee SC, Shao CL, Lee DR, Park SJ, Kwag GB, Choi KJ. Preparation and characterization of a nanoscale poly (vinyl alcohol) fiber aggregate produced by an electrospinning method. J Polym Sci B Polym Phys 2002 Jul 1;40(13):1261-8.
35. Peterson CT. Hybrid nanomanufacturing process for high-rate polymer nanofiber production. (MSc Thesis) University of Nebraska-Lincoln.
http://digitalcommons.unl.edu/engmechdiss/15 (2010). Accessed Dec 2010.
36. Lee JS, Choi KH, Ghim HD, Kim SS, Chun DH, Kim HY, Lyoo WS. :Role of molecular weight of atactic poly (vinyl alcohol)(PVA) in the structure and properties of PVA nanofabric prepared by electrospinning. J. Appl. Polym. Sci ,93(4),1638-1646 (2004).
37. Alobad ZK, Habeeb SA, Albozahid MA. A review on silicone rubber/montmorillo-nite nanocomposites. The Iraqi Journal for Mechanical and Materials Engineering. 2020;20(3):268-81.
38. Min BM, Lee G, Kim SH, Nam YS, Lee TS, Park WH. Electrospinning of silk fibroin nanofibers and its effect on the adhesion and spreading of normal human keratinocytes and fibroblasts in vitro. Biomaterials. 2004 Mar 1;25(7-8):1289-97.
39. Zhang C, Yuan X, Wu L, Han Y, Sheng J. Study on morphology of electrospun poly (vinyl alcohol) mats. Eur. Polym. J., 2005 Mar 1;41(3):423-32.
40. Wannatong L, Sirivat A, Supaphol P. Effects of solvents on electrospun polymeric fibers: preliminary study on polystyrene. Polym Int . ,2004 Nov;53(11):1851-9.
41. Subbiah T, Bhat GS, Tock RW, Parameswaran S, Ramkumar SS. Electrospinning of nanofibers. J. Appl. Polym. Sci . 2005 Apr 15;96(2):557-69.
42. LE KJ. Design of Aligned and Random Nanofibers for 3D Bi-functionalized Nerve Conduits Fabricated via a Novel Electrospinning Set-up. Sci. Rep. 2016;6:23761. ( 2016) .https:// doi: 10.1038/srep23761 .
43. Lai ES, Anderson CM, Fuller GG. Designing a tubular matrix of oriented collagen fibrils for tissue engineering. Acta Biomater . ,2011 Jun 1;7(6):2448-56.
44. Rahmani S, Rafizadeh M, Afshar Taromi F. Statistical analysis of nanofibers alignment in magnetic‐field‐assisted electrospinning including an alignment percentage formula. J. Appl. Polym. Sci., 2014 Dec 5;131(23).
45. Tahalyani J, Datar S, Balasubramanian K. Investigation of dielectric properties of free standing electrospun nonwoven mat. J. Appl. Polym. Sci. , 2018 Apr 20;135(16):46121.
46. Catena A, Guo Q, Kunze MR, Agnello S, Gelardi FM, Wehner S, Fischer CB. Morphological and chemical evolution of gradually deposited diamond-like carbon films on polyethylene terephthalate: from subplantation processes to structural reorganization by intrinsic stress release phenomena. ACS Appl. Mater. Interfaces .,2016 Apr 27;8(16):10636-46.
47. Zhou FL, Parker GJ, Eichhorn SJ, Cristinacce PL. Production and cross-sectional characterization of aligned co-electrospun hollow microfibrous bulk assemblies. Mater. Charact . ,2015 Nov 1;109:25-35.
2. Habeeb SA, Rajabi L, Dabirian F. Production of polyacrylonitrile/boehmite nanofibrous composite tubular structures by opposite‐charge electrospinning with enhanced properties from a low‐concentration polymer solution. Polym. Compos. 2020 Apr;41(4):1649-61.
3. Rafiei S, Maghsoodloo S, Noroozi B, Mottaghitalab V, Haghi AK. Mathematical modeling in electrospinning process of nanofibers: a detailed review. Cellul. Chem. Technol. 2013 May 1;47(5):323-38.
4. Habeeb SA, Alobad ZK, Albozahid MA. Effect of zinc oxide loading levels on the cure characteristics, mechanical and aging properties of the epdm rubber. International Journal of Mechanical Engineering and Technology (IJMET). 2019;10(1):133-41.
5. Yuan TT, DiGeorge Foushee AM, Johnson MC, Jockheck-Clark AR, Stahl JM. Development of electrospun chitosan-polyethylene oxide/fibrinogen biocomposite for potential wound healing applications. Nanoscale Res. Lett 2018 Dec;13(1):1-2.
6. Habeeb S, Rajabi L, Dabirian F. Comparing Two Electrospinning Methods in Producing Polyacrylonitrile Nanofibrous Tubular Structures with Enhanced Properties. Iran. J. Chem. Chem. Eng. 2019 Jun 1;38(3):23-42.
7. Shim IK, Jung MR, Kim KH, Seol YJ, Park YJ, Park WH, Lee SJ. Novel three‐dimensional scaffolds of poly (L‐lactic acid) microfibers using electrospinning and mechanical expansion: Fabrication and bone regeneration. J Biomed Mater Res B Appl Biomater. 2010 Oct;95(1):150-60.
8. Xiang P, Li M, Zhang CY, Chen DL, Zhou ZH. Cytocompatibility of electrospun nanofiber tubular scaffolds for small diameter tissue engineering blood vessels. International J. Biol. Macromol. 2011 Oct 1;49(3):281-8.
9. Habeeb SA, Alobad ZK, Albozahid MA. The Effecting of Physical Properties of Inorganic Fillers on Swelling Rate of Rubber Compound: A review Study. Journal of University of Babylon for Engineering Sciences. 2019 Jan 28;27(1):94-104.
10. Dabirian F, Hosseini SA. Novel method for nanofibre yarn production using two differently charged nozzles. Fibres Text. East. Eur. 2009 Jul 1;17(3):45-7.
11. Chen J, Niu Q, Chen G, Nie J, Ma G. Electrooxidation of methanol on Pt@ Ni bimetallic catalyst supported on porous carbon nanofibers. J. Phys. Chem. C. 2017 Jan 26;121(3):1463-71.
12. Albozahid M, Diwan AA, Habeeb SA. The effect of addition graphite filler on mechanical properties of epoxy material. Egyptian Journal of Chemistry. 2021 Oct 1;64(10):5747-54.
13. Mottaghitalab V, Haghi AK. A study on electrospinning of polyacrylonitrile nanofibers. Korean J. Chem. Eng . 2011 Jan;28:114-8.
14. Garg K, Bowlin GL. Electrospinning jets and nanofibrous structures. Biomicrofluidics. 2011 Mar 30;5(1):013403.
15. Zong X, Kim K, Fang D, Ran S, Hsiao BS, Chu B. Structure and process relationship of electrospun bioabsorbable nanofiber membranes. polymer. 2002 Jul 1;43(16):4403-12.
16. Habeeb SA. Impact of Polymeric Solutions Parameters on Morphological Properties of Composite Nanofibers. Journal of University of Babylon for Engineering Sciences. 2021 Oct 24;29(2):115-20.
17. Jacobs V, Anandjiwala RD, Maaza M. The influence of electrospinning parameters on the structural morphology and diameter of electrospun nanofibers. . J. Appl. Polym. Sci, 2010 Mar 5;115(5):3130-6.
18. Ren C. PAN nanofibers and nanofiber reinforced composites, ( M.S. Thesis) University of Nebraska-Lincoln . https://digitalcommons.unl.edu/mechengdiss/59/ ( 2013). Accessed Aug 2013.
19. Panda PK. Ceramic nanofibers by electrospinning technique—A review. T INDIAN CERAM SOC, 2007 Apr 1;66(2):65-76.
20. Deitzel JM, Kleinmeyer J, Harris DE, Tan NB. The effect of processing variables on the morphology of electrospun nanofibers and textiles. Polymer. 2001 Jan 1;42(1):261-72.
21. Habeeb SA, Hasan AS, Ţălu Ş, Jawad AJ. Enhancing the Properties of Styrene-Butadiene Rubber by Adding Borax Particles of Different Sizes. Iran. J. Chem. Chem. Eng. Res. Artic. 2021;40(5).
22. Jalili R, Morshed M, Ravandi SA. Fundamental parameters affecting electrospinning of PAN nanofibers as uniaxially aligned fibers. J. Appl. Polym. Sci., 2006 Sep 15;101(6):4350-7.
23. Thompson CJ, Chase GG, Yarin AL, Reneker DH. Effects of parameters on nanofiber diameter determined from electrospinning model. Polymer. 2007 Nov 2;48(23):6913-22.
24. Wang L, Chang MW, Ahmad Z, Zheng H, Li JS. Mass and controlled fabrication of aligned PVP fibers for matrix type antibiotic drug delivery systems. Chem. Eng.J, 2017 Jan 1;307:661-9.
25. Dippold D, Cai A, Hardt M, Boccaccini AR, Horch R, Beier JP, Schubert DW. Novel approach towards aligned PCL-Collagen nanofibrous constructs from a benign solvent system. . Mater. Sci. Eng. C . 2017 Mar 1;72:278-83.
26. Shalumon KT, Anjana J, Mony U, Jayakumar R, Chen JP. Process study, development and degradation behavior of different size scale electrospun poly (caprolactone) and poly (lactic acid) fibers. J POLYM RES ., 2018 Mar;25:1-9.
27. Abdulkadhim MK, Habeeb SA. The Possibility of Producing Uniform Nanofibers from Blends of Natural Biopolymers., Materials Performance and Characterization 11(1) (,313-323(2022). https://doi.org/10.1520/MPC20220045
28. Faris D, Hadi NJ, Habeeb SA. Effect of rheological properties of (Poly vinyl alcohol/Dextrin/Naproxen) emulsion on the performance of drug encapsulated nanofibers. Materials Today: Proceedings. 2021 Jan 1;42:2725-32.
29 Habeeb SA, Nadhim BA. Removal of Nickel (II) Ions, Low Level Pollutants, and Total Bacterial Colony Count from Wastewater by Composite Nanofibers Film. Sci. Iran. , 2022 Oct 24.
30. Nadhim BA, Habeeb SA. Studying the Physical Properties of Non-Woven Polyacrylonitrile Nanofibers after Adding γ-Fe2O3 Nanoparticles. Egypt. J. Chem.. 2021 Dec 1;64(12):7621-30.
31. Bonani W, Maniglio D, Motta A, Tan W, Migliaresi C. Biohybrid nanofiber constructs with anisotropic biomechanical properties. J Biomed Mater Res B Appl Biomater., 2011 Feb;96(2):276-86.
32. Sreedhara SS, Tata NR. A novel method for measurement of porosity in nanofiber mat using pycnometer in filtration. J Eng Fiber Fabr., 2013 Dec; 8(4) : 155892501300800408.
33. Boppa, V: Characterization of Structure and Tensile Properties of Electrospun Web. (MSc Thesis) Faculty of North Carolina State University, Raleigh, North Carolina. http://www.lib.ncsu.edu/resolver/1840.16/1485 (2009) . Accessed 7 Dec 2009.
34. Ding B, Kim HY, Lee SC, Shao CL, Lee DR, Park SJ, Kwag GB, Choi KJ. Preparation and characterization of a nanoscale poly (vinyl alcohol) fiber aggregate produced by an electrospinning method. J Polym Sci B Polym Phys 2002 Jul 1;40(13):1261-8.
35. Peterson CT. Hybrid nanomanufacturing process for high-rate polymer nanofiber production. (MSc Thesis) University of Nebraska-Lincoln.
http://digitalcommons.unl.edu/engmechdiss/15 (2010). Accessed Dec 2010.
36. Lee JS, Choi KH, Ghim HD, Kim SS, Chun DH, Kim HY, Lyoo WS. :Role of molecular weight of atactic poly (vinyl alcohol)(PVA) in the structure and properties of PVA nanofabric prepared by electrospinning. J. Appl. Polym. Sci ,93(4),1638-1646 (2004).
37. Alobad ZK, Habeeb SA, Albozahid MA. A review on silicone rubber/montmorillo-nite nanocomposites. The Iraqi Journal for Mechanical and Materials Engineering. 2020;20(3):268-81.
38. Min BM, Lee G, Kim SH, Nam YS, Lee TS, Park WH. Electrospinning of silk fibroin nanofibers and its effect on the adhesion and spreading of normal human keratinocytes and fibroblasts in vitro. Biomaterials. 2004 Mar 1;25(7-8):1289-97.
39. Zhang C, Yuan X, Wu L, Han Y, Sheng J. Study on morphology of electrospun poly (vinyl alcohol) mats. Eur. Polym. J., 2005 Mar 1;41(3):423-32.
40. Wannatong L, Sirivat A, Supaphol P. Effects of solvents on electrospun polymeric fibers: preliminary study on polystyrene. Polym Int . ,2004 Nov;53(11):1851-9.
41. Subbiah T, Bhat GS, Tock RW, Parameswaran S, Ramkumar SS. Electrospinning of nanofibers. J. Appl. Polym. Sci . 2005 Apr 15;96(2):557-69.
42. LE KJ. Design of Aligned and Random Nanofibers for 3D Bi-functionalized Nerve Conduits Fabricated via a Novel Electrospinning Set-up. Sci. Rep. 2016;6:23761. ( 2016) .https:// doi: 10.1038/srep23761 .
43. Lai ES, Anderson CM, Fuller GG. Designing a tubular matrix of oriented collagen fibrils for tissue engineering. Acta Biomater . ,2011 Jun 1;7(6):2448-56.
44. Rahmani S, Rafizadeh M, Afshar Taromi F. Statistical analysis of nanofibers alignment in magnetic‐field‐assisted electrospinning including an alignment percentage formula. J. Appl. Polym. Sci., 2014 Dec 5;131(23).
45. Tahalyani J, Datar S, Balasubramanian K. Investigation of dielectric properties of free standing electrospun nonwoven mat. J. Appl. Polym. Sci. , 2018 Apr 20;135(16):46121.
46. Catena A, Guo Q, Kunze MR, Agnello S, Gelardi FM, Wehner S, Fischer CB. Morphological and chemical evolution of gradually deposited diamond-like carbon films on polyethylene terephthalate: from subplantation processes to structural reorganization by intrinsic stress release phenomena. ACS Appl. Mater. Interfaces .,2016 Apr 27;8(16):10636-46.
47. Zhou FL, Parker GJ, Eichhorn SJ, Cristinacce PL. Production and cross-sectional characterization of aligned co-electrospun hollow microfibrous bulk assemblies. Mater. Charact . ,2015 Nov 1;109:25-35.
